Wednesday, December 14, 2022
In the Fe–Fe2Nb system, at 1373°C, of 3% Nb, liquid of 12% Nb and of 27% Nb are in equilibrium. At 1210°C, of 1% Nb, of 1.5% Nb and of 27% Nb are in equilibrium. At 961°C, of 0.4% Nb, of 0.7% Nb and of 27% Nb are in equilibrium. All compositions are in atomic%. The melting point of Fe is 1535°C and of Fe2Nb (33.3 at.% Nb) is 1627°C. The phase is stable over a composition range of 27 to 33.3 at.% Nb, (i) Draw an approximate phase diagram for this system. (ii) Write down the invariant reactions in the system, giving their names. (iii) What is the fraction of in an alloy with 10% Nb at 960°C?
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